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Phys 498CQM Lecture Notes 19
Part IV: Many-Body problems in Quantum Mechanics: Introduction

Monday, April 2, 2001
Lecturer: Richard Martin

Reading:
Skim ideas in
Thijssen, Ch. 12-13

  1. Many-Body problems - Introduction to remainder of course
    • The many-body wavefunction for electrons
      • The general form of the wavefunction discussed in lecture 7
      • Reminder of the simplification in the Hartree-Fock Approximation
      • How can we do better - how to include correlations?
      • The idea is a correlated wavefunction like that for the H2 molecule discussed in Thijssen, 12.2.
      • This leads up to the use of Monte Carlo methods
    • Idealized many-body problems - examples
      • The Hubbard model model for electrons
      • Simplest example: Heitler-London theory for H2
      • Spin models - Ising, Heisenberg
      • The key point is that the size of the Hilbert space grows as a factorial of the number of possible states for one particle
      • Exact solutions only possible for very restricted numbers of single body orbitals, and limited numbers of particles in systems
      • Configuration interaction methods in chemistry
      • Monte Carlo methods sample large spaces by random methods
      • Lanczos methods are efficient methods to find lowest eigenstates of enormous matrices

Next time: Monte Carlo methods for Quantum Problems: Thijssen Chapt. 12


Last Modified March 28
Email question/comments/corrections to rmartin@uiuc.edu .